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Highly efficient Tris(trimethylsilyl)silane (TTMSS) CAS 1873-77-4 for versatile organic synthesis and superior safety
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Highly efficient Tris(trimethylsilyl)silane (TTMSS) CAS 1873-77-4 for versatile organic synthesis and superior safety
| MOQ: | サンプルは500g、1kgまたは25kg、業務用は1000kg |
| 標準梱包: | 正味重量 25kg または 200kg/パッケージ |
| 配達期間: | 3営業日以内 |
| 支払方法: | T/T、LC、OA |
| 供給能力: | 3000トン/月 |
詳細情報
起源の場所
中国山西省
ブランド名
Zorui
証明
ISO, COA, MSDS, TDS, AAA
モデル番号
1873-77-4
名前:
トリス(トリメチルシリル)シラン (TTMSS)
CAS:
1873-77-4
純度:
≥ 99%
重金属:
≤ 10ppm
微生物 の 限界:
標準仕様を満たしています
保管条件:
光を避け、涼しく乾燥した場所に保管してください
貯蔵寿命:
適切に保管した場合、通常 2 ～ 3 年
サンプル:
利用可能
ポート:
天津、上海、青島、その他中国の港
貿易条件:
EXW、DAP、FOB、CFR、CIF、CPT、CIP
配送:
サンプルは特急、100kg以上は航空、1000kg以上は海上で
ストレージ:
涼しく乾燥した換気の良い場所。湿気や高温を避ける
製品の説明
Tris(trimethylsilyl)silane (TTMSS) CAS 1873-77-4
Tris(trimethylsilyl)silane (TTMSS) CAS 1873-77-4
Product Introduction
Tris(trimethylsilyl)silane (TTMSS) is a highly efficient and versatile organosilicon reducing agent and radical mediator. With the CAS number 1873-77-4, it is a cornerstone compound in advanced organic synthesis and materials science. TTMSS is renowned for its ability to facilitate smooth radical-based reactions, including reductions, dehalogenations, and hydrosilylation processes, under mild conditions. It offers superior selectivity and safety compared to traditional reducing agents like tributyltin hydride, making it a preferred choice in modern laboratory and industrial applications.
Physical and Chemical Specifications
| CAS Number | 1873-77-4 |
|---|---|
| Molecular Formula | Si₄C₉H₂₈ or [(CH₃)₃Si]₃SiH |
| Molecular Weight | 244.62 g/mol |
| Appearance | Clear, colorless to pale yellow liquid |
| Boiling Point | ~80-82 °C (at 10 mmHg) |
| Flash Point | >100 °C |
| Density | ~0.83 g/cm³ at 25 °C |
| Refractive Index | n₂₀/D ~1.460 |
| Solubility | Soluble in common organic solvents (THF, hexane). Insoluble in water. |
| Stability | Stable under inert atmosphere (N₂, Ar). Moisture-sensitive. |
| Storage Condition | Store under dry, inert gas at 2-8 °C. |
| Typical Assay (by GC) | ≥98% |
Product Functions
- Radical Reducing Agent: Efficiently reduces halides (Cl, Br, I), selenides, and other radical precursors to the corresponding hydrocarbons.
- Radical Mediator: Initiates and propagates radical chain reactions in polymerization and functionalization.
- Hydrosilylation Agent: Adds Si-H group across unsaturated bonds (C=C, C=O) under radical conditions.
- Dehalogenation Agent: Cleanly removes halogen atoms from organic molecules without strong bases or metals.
- Hydrogen Source: Provides a mild and selective source of hydrogen for radical reactions.
Application Areas
- Organic Synthesis: Key intermediate in the synthesis of complex molecules, and natural products. Used for dehalogenation in multi-step sequences.
- Polymer Science & Radical Polymerization: As a radical initiator/chain transfer agent for controlled polymerization (e.g., RAFT) and synthesis of functional polymers.
- Materials Chemistry: Surface modification, preparation of silicon-based materials and nanocomposites.
- Radical Chemistry Research: Fundamental tool in mechanistic studies and development of new radical methodologies.
- Lab Automation & Flow Chemistry: Suitable for continuous processes due to its liquid form and predictable reactivity.
Manufacturing Process
TTMSS is manufactured through a high-purity, multi-step synthesis under stringent controlled conditions:
- Starting Materials: High-quality chlorosilanes and metallic silicon.
- Silylation Reaction: Stepwise silylation under inert atmosphere to build the tris(trimethylsilyl) structure.
- Hydride Formation: Introduction of the reactive Si-H moiety via precise reduction or substitution.
- Purification: Involves advanced distillation, filtration, and chromatography to remove any metallic, halide, or oligomeric impurities.
- Quality Control: Rigorous analytical testing (GC, NMR, FTIR) ensures consistency, purity, and performance.
Why Choose Us
- Ultra-High Purity: Our TTMSS consistently assays at ≥98%, ensuring reliable and reproducible reaction outcomes.
- Technical Expertise: Backed by deep synthetic chemistry knowledge and dedicated R&D support.
- Batch-to-Batch Consistency: Stringent QC protocols guarantee identical performance across every order.
- Safe & Secure Packaging: Supplied in sealed, septum-capped vials or ampoules under inert gas for maximum stability.
- Global Logistics: Efficient worldwide shipping with full regulatory documentation and safety data sheets.
- Competitive Pricing: Cost-effective solutions without compromising on quality or service.
FAQ
Q1: Is TTMSS safer than tributyltin hydride?
A: Yes. TTMSS is non-toxic, avoids toxic tin residues, and is easier to handle, making it a safer and environmentally friendlier alternative.
Q2: What reactions can TTMSS replace tin hydride in?
A: It effectively replaces tin hydride in almost all radical reductions, including dehalogenations, reductive cyclizations, and desulfurizations.
Q3: How should TTMSS be stored and handled?
A: Store under dry nitrogen or argon at 2-8°C. Always handle with standard anhydrous techniques using syringes or cannula to prevent moisture exposure.
Q4: Can TTMSS be used in aqueous or protic media?
A: No. TTMSS is moisture-sensitive and reacts violently with water or alcohols. It must be used in anhydrous organic solvents.
Q5: What is the typical reaction temperature for TTMSS?
A: Reactions are often conducted at room temperature or mild heating (50-80°C), frequently using UV light or a radical initiator like AIBN.
Q6: Do you offer technical support for using TTMSS?
A: Absolutely. We provide detailed application notes, reaction protocols, and direct access to our technical team for consultation.
Q7: Is bulk/industrial quantity available?
A: Yes. We supply from gram-scale laboratory quantities to multi-kilogram industrial batches. Contact us for a custom quote.
Q8: What documentation is provided?
A: Each shipment includes Certificate of Analysis (CoA), Material Safety Data Sheet (MSDS/SDS), and full chemical documentation.
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